Robert D. Ballard is Founder and President of the Ocean Exploration Trust; Director of the Center for Ocean Exploration and Professor of Oceanography at the University of Rhode Island Graduate School of Oceanography. He is an Explorer-At-Large at the National Geographic Society, Commissioner for the U.S. Commission on Ocean Policy, and a Research Scholar at the Woods Hole Oceanographic Institution. Yet surprisingly little is known about how much mercury in the environment is the result of human activity, or even how much bioavailable mercury exists in the global ocean. Methylmercury is the only form of mercury that accumulates appreciably in fish. Williams and her crewmates are working closely with Boeing to develop their new spacecraft systems, which will provide roundtrip crew transportation services to the International Space Station and, along with SpaceX’s CrewDragon, return the ability to launch humans into space from United States soil. To obtain estimates for shallower waters and to provide basin-wide numbers for the amount of mercury in the global ocean, the team needed a tracer—a substance that could be linked back to the major activities that release mercury into the environment in the first place. mercury moves and changes form in the environment. Phosphate is a nutrient that, like mercury, is taken up into the marine food web by binding with organic material. In recent years, biologists have been tracking mercury’s footprints in unexpected habitats and species. His most recent book, The Shark Handbook, is a must buy for all shark enthusiasts. Analyses of such biochemical indicators indicate that mercury is adversely affecting diving ducks from the San Francisco Bay, herons and egrets from the Carson River, Nevada, and heron embryos from colonies along the Mississippi River. Kirstin Meyer-Kaiser is an Assistant Scientist in the Biology Department at Woods Hole Oceanographic Institution. For more information, please visit www.whoi.edu. Lake acidification, addition of substances like sulfur that stimulate methylation, and mobilization of mercury in soils in newly flooded reservoirs or constructed wetlands have been shown to increase the likelihood that mercury will become a problem in fish. Dr. Gregory Skomal is an accomplished marine biologist, underwater explorer, photographer, and author. For information on USGS products and services, visit the USGS home page at www.usgs.gov or ask.usgs.gov, or call 1-888- ASK-USGS, or use the Ask USGS fax service, which is available 24 hours Alkali and metal processing, incineration of coal, and medical and other waste, and mining of gold and mercury contribute greatly to mercury concentrations in some areas, but atmospheric deposition is the dominant source of mercury over most of the landscape. from the University of Auckland, and Ph.D. from James Cook University, North Queensland, Australia. Mercury is a naturally occurring element as well as a by-product of such distinctly human enterprises as burning coal and making cement. Mercury levels in the Pacific Ocean are rising, a new study suggests. Mercury levels in surface ocean have tripled. “At the moment, however, there is no way to look at a water sample and tell the difference between mercury that came from pollution and mercury that came from natural sources. Even the deepest parts of the ocean have not escaped unscathed. (Illustration by Jack Cook, Woods Hole Oceanographic Institution), A CTD (conductivity, temperature, depth) rosette is lowered over the side of R/V Knorr during the North Atlantic GEOTRACES cruise in 2011. In addition, they found that ocean waters shallower than about 100 m (300 feet) have tripled in mercury concentration since the Industrial Revolution and that the ocean as a whole has shown an increase of roughly 10 percent over pre-industrial mercury levels. The conversion of inorganic mercury to methylmercury There is a global reservoir of airborne mercury circulating worldwide at any one time. People are exposed to methylmercury almost entirely by eating contaminated fish and wildlife that are at the top of aquatic foodchains. Mercury can cause deformities in developing animals. Natural sources of atmospheric mercury include volcanoes, geologic deposits of mercury, and volatilization from the ocean. Mercury concentrations are high enough to trigger fish consumption advisories in many States. These methylmercury-containing bacteria may be consumed by the next A new paper by a group that includes researchers from the Woods Hole Oceanographic Institution (WHOI), Wright State University, Observatoire Midi-Pyréneés in France, and the Royal Netherlands Institute for Sea Research appears in this week’s edition of the journal Nature and provides the first direct calculation of mercury in the global ocean from pollution based on data obtained from 12 sampling cruises over the past 8 years. He is also adjunct faculty at the University of Massachusetts School for Marine Science and Technology and an adjunct scientist at the Woods Hole Oceanographic Institution (WHOI). Salt content in the tips for boating in the Ocean can also cause mercury in sea water. Timothy Shank is a deep-sea biologist, Associate Scientist in the Biology Department, and former Director of the Ocean Exploration Institute at the Woods Hole Oceanographic Institution. Mercuric chloride is used in photography and as a topical antiseptic and disinfectant, wood preservative, and fungicide. Older fish also have higher mercury levels due to the same reason. Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. Mercury pollution is now identified as a global problem and awareness has been raised on an international action plan to minimize anthropogenic mercury emissions and clean up mercury pollution. … Established in 1930 on a recommendation from the National Academy of Sciences, its primary mission is to understand the ocean and its interaction with the Earth as a whole, and to communicate a basic understanding of the ocean’s role in the changing global environment. Mercury occurs naturally in the earth’s crust, but human activities, such as mining and fossil fuel combustion, have led to widespread global mercury pollution. 1. “With the increases we’ve seen in the recent past, the next 50 years could very well add the same amount we’ve seen in the past 150,” said Lamborg. During the past decade, a new trend has emerged with regard to mercury pollution. His honors include 22 Honorary Doctorates, National Geographic’s highest award, the Hubbard Medal, and a National Endowment for the Humanities Medal. Sunlight can break down methylmercury to Hg(II) or Hg(0), which can leave the Although scientists from USGS and elsewhere are beginning to unravel the complex interactions between mercury and the environment, a lack of information on the sources, behavior, and effects of mercury in the environment has impeded identification of effective management responses to the Nation's growing mercury problem. It is difficult to prove cause and effect in field studies, however, because other factors that may contribute to the biological Coastal areas along the Gulf of Mexico, Maine, and the Atlantic Ocean from Florida through North Carolina are under advisories for methylmercury for certain fish. Large tuna can have elevated levels of mercury because of their high rank in ocean food chain. Although all rocks, sediments, water, and soils naturally contain small but varying amounts of mercury, scientists have found some local mineral occurrences and thermal springs that are naturally high in mercury. Studies have shown that for the same species of fish taken from He is known for his research on the ecology and evolution of fauna in deep-ocean hydrothermal, seamount, canyon and deep trench systems. Analysis of their results showed rough agreement with the models used previously—that the ocean contains about 60,000 to 80,000 tons of pollution mercury. With much of his work in the South Pacific and Caribbean, Simon has been on many cruises, logging 1,000 hours of scuba diving and 800 hours in tropical environs. Atmospheric deposition contains the three principal forms of mercury, although inorganic divalent mercury Privacy Mercury is a neurotoxin that settles into the ocean in large concentrations after we spew it out of industrial smokestacks when burning fossil fuels like coal and oil. Some sites may have become methylmercury hot spots inadvertently through human activities. Once in surface water, mercury enters a complex cycle in which one form can be converted to another. locations remote from point sources, mercury biomagnification can result in toxic effects in consumers at the top of these aquatic food chains. December 19, 2020 — Dan Schlenoff Although the use of mercury salts in consumer products, such as medicinal products, have been discontinued, inorganic mercury compounds are still being widely used in skin lightening soaps and creams. Sampling mercury in water requires extra care to avoid cross contamination because concentrations in water are so low. But determining the contribution of mercury from human activity required another step. FOIA Nov. 10, 2016 — For years, public health experts have warned against eating certain kinds of fish, including tuna, that tend to accumulate mercury. It’s an … The Woods Hole Oceanographic Institution is dedicated to advancing knowledge of the ocean and its connection with the Earth system through a sustained commitment to excellence in science, engineering, and education, and to the application of this knowledge to problems facing society. He was elected a Fellow of the American Academy of Arts and Sciences in 2014. Databases of CO2 in ocean waters are extensive and readily available for every ocean basin at virtually all depths. Kirstin also has ongoing projects in the Arctic and on coral reefs in Palau. In North American sediment cores, sediments deposited since industrialization have mercury concentrations about 3-5 times those found in older sediments. By determining the ratio of phosphate to mercury in water deeper than 1,000 meters (3,300 feet) that has not been in contact with Earth’s atmosphere since the Industrial Revolution, the group was able to estimate mercury in the ocean that originated from natural sources such as the breakdown, or “weathering,” of rocks on land. concentrations of methy-lmercury can thus readily accumulate to potentially harmful concentrations in fish, fish-eating wildlife and people. Research has shown that mercury can also spread in the ocean through … The key is now we have some solid numbers on which to base continued work.”, “Mercury is a priority environmental poison detectable wherever we look for it, including the global ocean abyss,” says Don Rice, director of the National Science Foundation (NSF)’s Chemical Oceanography Program, which funded the research. He recently discovered that blue sharks use warm water ocean tunnels, or eddies, to dive to the ocean twilight zone, where they forage in nutrient-rich waters hundreds of meters down. Although it is less toxic than methylmercury, Media Relations Office Now we have a way to at least separate the bulk contributions of natural and human sources over time.”. They found it in one of the most well studied gases of the past 40 years—carbon dioxide. media@whoi.edu Scientists have discovered toxic effects in the field at concentrations of mercury that are toxic in the lab, and controlled lab studies have found toxic effects at concentrations that are common in certain environments. Kirstin is currently Principal Investigator for an interdisciplinary project on shipwrecks in Stellwagen National Marine Sanctuary, including the steamship Portland, often termed “New England’s Titanic.” This project uses cutting-edge technology to construct 3D photogrammetric models of the Portland and other wrecks for archaeological and biological research and resource management. other contaminants also affect the toxicity of mercury. The sea has a high salt levels usually also have mercury content of the same magnitude. In several areas of the United States, concentrations of mercury in fish and wildlife are high enough to be a risk to wildlife. The higher the fish ranks in the food chain, the more mercury exposed fish it consumes, thus the higher its mercury levels will eventually be. Mercury is able to travel long distances in the air. Exposure to methylmercury is usually by ingestion, and it is absorbed more readily and excreted more slowly than other forms of mercury. One result is that intermediate levels of the ocean (between 100 and 1,000 meters depth) are also enriched in mercury up to 2.5 times the natural background rate. He served in the U.S. Navy for more than 30 years and continues to work with the Office of Naval Research. Investigations initiated in the late 1980's in the northern-tier states of the U.S., Canada, and Nordic countries found that fish, mainly from nutrient-poor lakes and often in very remote areas, commonly have high levels of mercury. Mercury itself isn’t a bogeyman, as it occurs naturally at low levels in rock, soil and water throughout the world. Bacteria that process sulfate (SO4=) in the environment take up mercury in its inorganic form and convert it to methylmercury through metabolic processes. The atmosphere is a major source of mercury in the ocean, and as the element makes its way from the air to the sea, it infiltrates marine food webs. Mercuryis a toxic heavy metal which cycles through the atmosphere, water and soil in various forms to different parts of the world. Ingestion of other common forms of mercury, such as the salt HgCl2, which damages the gastrointestinal tract and causes kidney failure, is unlikely from environmental sources. Mercury attached to particles can settle onto the sediments Aside from grossly polluted environments, mercury is normally a problem only where the rate of natural formation of methylmercury from inorganic mercury is greater than the reverse reaction. Mercury is a highly toxic element that is found both naturally and as an introduced contaminant in the environment. People have been extracting mercury from cinnabar since at least Roman times. Loons are especially vulnerable to methyl-mercury because a high percentage of their diet is fish. 3.3 How may certain ecosystems be affected? Greg has been an avid SCUBA diver and underwater photographer since 1978. The Tropical and Northeast Pacific, on the other hand, were seen to be relatively unaffected because it takes centuries for deep ocean water to circulate to those regions. Where is mercury found? What are the impacts of mercury on human health? One result is that intermediate levels of the ocean (between 100 and 1,000 meters depth) are also enriched in mercury up to 2.5 times the natural background rate. Her work frequently takes her underwater using remotely operated vehicles and SCUBA and carries her to the far corners of the world. effect under study (for example, reproductive success) are often impossible to control. now account for more than three-quarters of all fish consumption advisories in the United States. is important because its toxicity is greater and because organisms require considerably longer to eliminate methylmercury. For more information on USGS research on mercury, visit methylmercury. Methylmercury can be more harmful to bird embryos when selenium, another potentially toxic element, is present in the diet. “It would seem that, if we want to regulate the mercury emissions into the environment and in the food we eat, then we should first know how much is there and how much human activity is adding every year,” said Lamborg, who has been studying mercury for 24 years. Her work frequently takes her underwater using remotely operated vehicles and SCUBA and carries her to the far corners of the world. In 1985, he discovered the RMS Titanic, and has succeeded in tracking down numerous other significant shipwrecks, including the German battleship Bismarck, the lost fleet of Guadalcanal, the U.S. aircraft carrier Yorktown, and John F. Kennedy’s boat, PT-109. Where do the world's supplies of mercury come from? Although all rocks, sediments, water, and soils naturally contain small but varying amounts of mercury, scientists have found some local mineral occurrences and thermal springs that are naturally high in mercury. Data and water samples collected during the cruise contributed to the study of mercury in the global ocean led by Carl Lamborg. aquatic environment and reenter the atmosphere as a gas. The concentration of dissolved organic carbon (DOC) and pH have a strong effect on the ultimate fate of mercury in an ecosystem. He uses techniques that span isotope geochemistry, next generation DNA sequencing, and satellite tagging to study the ecology of a wide variety of ocean species. Tilefish (Gulf of Mexico) – Containing a whopping average 219 micrograms of mercury, the tilefish … From there, rainfall washes the mercury into the ocean. Therefore, certain people should take extra care. This is the second paper that has linked mercury on the ocean floor with human activity. (©Copyright Woode Hagge; used with permission. U.S. Geological Survey Humans have a way of seriously messing things up. He is the author of the award-winning, best-selling book “Discovering the Deep.”. The report went on to estimate that more than 60,000 children are born each year at risk for adverse neurodevelopmental effects due to in utero exposure to and the senses of touch, taste, and sight. Policies and Notices, U.S. Department of the Interior | How Does Mercury Get into Fish and Seafood? Once in the ocean, mercury adheres to organic particles and sinks or is consumed by progressively larger marine animals. The FDA suggests that any woman of child-bearing age, from age 16 to 49, to also avoid eating fish that has the highest mercury levels. Finally, Simon Thorrold is an ocean ecologist at Woods Hole Oceanographic Institution. 4. Their findings agreed with what they would expect to see given the known pattern of global ocean circulation. The group started by looking at data sets that offer detail about oceanic levels of phosphate, a substance that is both better studied than mercury and that behaves in much the same way in the ocean. Estimates of “bioavailable” mercury—forms of the element that can be taken up by animals and humans—play an important role in everything from drafting an international treaty designed to protect humans and the environment from mercury emissions, to establishing public policies behind warnings about seafood consumption. Much of his current research centers on the use of acoustic telemetry and satellite-based tagging technology to study the ecology and behavior of sharks. 1 The increase may mean that more methylmercury, a human neurotoxin formed when mercury … Bacteria in lake, stream, and ocean sediments then convert elemental mercury into organic mercury compounds such as methylmercury. concentrations that are typical of parts of the Everglades, the behavior of juvenile great egrets can be affected. the same region, increasing the acidity of the water (decreasing pH) and/or the DOC content generally results in higher mercury levels in fish, an indicator of greater net methylation. Many types of fish are rich in omega-3 fatty acids that have been linked to a number of health benefits, but some popular species, such as swordfish, king mackerel, shark and some tuna, contain significant levels of mercury. Accessibility 3.2 How is wildlife affected? 90% He holds a master’s degree from the University of Rhode Island and a Ph.D. from Boston University. Small environmental The toxic effects of mercury depend on its chemical form and the route of exposure. Methylation is a product of complex processes that move and transform mercury. The Woods Hole Oceanographic Institution is a private, independent organization on Cape Cod, Mass., dedicated to marine research, engineering, and higher education. In the 1950s, a neurological epidemic killed thousands of villagers in … Methylmercury [CH3Hg] is the most toxic form. This orthographic projection view provides a look at Mercury's north polar region. The risk is determined by the likelihood of exposure, the form of mercury present (some forms are more toxic than others), and the geochemical and ecological factors that influence how What is mercury? (Photo by Ken Kostel, Woods Hole Oceanographic Institution), Researchers led by Carl Lamborg at the Woods Hole Oceanographic Institution found that mercury from human activity (primarily atmospheric emissions produced by coal burning and cement production, as well as gold mining) have resulted in ocean waters down to 100 meters depth being enriched in the toxic element up to 3.5 times the background level caused by the natural breakdown, or weathering, of rocks on land. She is currently training for the first post-certification mission of Boeing’s Starliner spacecraft – the second crewed flight for that vehicle – and her third long duration mission aboard the International Space Station. Although mercury is a globally dispersed contaminant, it is not a problem everywhere. a day at 703-648-4888. Natural sources of atmospheric mercury include volcanoes, geologic deposits of mercury, and volatilization from the ocean. He is a Boston Sea Rover and a member of The Explorers Club; his home and laboratory are on the south coast of Massachusetts. 3. In studies in Wisconsin, reductions in loon chick production has been found in lakes where mercury concentrations in eggs exceed concentrations that are toxic in laboratory studies. (Photo by Brett Longworth, Woods Hole Oceanographic Institution). Fur of Sea Lions and Seals. Even at very low atmospheric deposition rates in Higher acidity and DOC levels enhance the mobility of mercury in the environment, thus making it more likely to enter the food chain. (Photo by Brett Longworth, Woods Hole Oceanographic Institution), A McLane pump being deployed from R/V Thompson during the West Pacific GEOTRACES cruise in 2013 helped researchers gather small particles of organic matter to which mercury attaches and sinks to intermediate depths (100 to 1,000 meters) in the ocean. The planet nearest the sun has a diameter about two-fifths that of Earth and gravity about 38 percent as strong as ours. ), Environments Where Methylmercury is a Problem, Mercury Contamination - Past, Present, and Future. Environments that are known to favor the production of methylmercury include certain types of wetlands, dilute low-pH lakes in Northeast and Northcentral United States, parts of the Florida Everglades, newly flooded reservoirs, and coastal wetlands, particularly along the Gulf of Mexico, Atlantic Ocean, and San Francisco Bay. Read our, and more than 100 dives with autonomous underwater and remotely-operated vehicles, including the first use of a hybrid ROV, He is the author of the award-winning, best-selling book “. This is not just a scourge of modern life; Lamborg said a mercury mine in Slovenia has been dumping its wastewater into … Due to this natural cycle, irrespective of which part of the world releases mercury it could affect an entirely different part of the world making mercury pollution a global concern. Elemental mercury, Hg(0), the form released from broken thermometers, causes tremors, gingivitis, and excitability when vapors are inhaled over a long period of time. Indicate that total mercury levels in the North Pacific Ocean water have risen about 30 percent over the last 20 years. If elemental mercury is ingested, it is absorbed relatively slowly and may pass through the digestive system without causing damage. His shark research has spanned the globe from the frigid waters of the Arctic Circle to coral reefs in the tropical Central Pacific. Mercury emitted into the air eventually settles into water or onto land where it can be washed into water. What are the impacts of mercury on the environment? © 2020 Woods Hole Oceanographic Institution, We use cookies to analyze site usage and improve user experience. He has been a fisheries scientist with the Massachusetts Division of Marine Fisheries since 1987 and currently heads up the Massachusetts Shark Research Program. For more than 30 years, Greg has been actively involved in the study of life history, ecology, and physiology of sharks. In highly polluted areas where mercury has accumulated through industrial or mining activities, natural processes may bury, dilute, or erode the mercury deposits, resulting in declines in concentration. “The trouble is, we don’t know what it all means for fish and marine mammals. Forty States have issued advisories for methylmercury on selected water-bodies and 13 states have statewide advisories for some or all sportfish from rivers or lakes. Page Contact Information: Ask USGS where it can diffuse into the water column, be resuspended, be buried by other sediments, or be methylated. A pioneer in the development of deep-sea submersibles and remotely operated vehicle systems, he has taken part in more than 155 deep-sea expeditions. Sunita L. Williams (Suni) was selected as an astronaut by NASA in 1998 and is a veteran of two space missions Expeditions 14/15 and 32/33. Mercury has the most eccentric orbit of any planet, with a … Once in the atmosphere, mercury is widely disseminated and can circulate for years, accounting for its wide-spread distribution. of international trade TRADE travels by ship. URL: http://www.usgs.gov/themes/factsheet/146-00/index.html Nov. 10, 2016 — For years, public health experts have warned against eating certain kinds of fish, including tuna, that tend to accumulate mercury. But human activities have increased total mercury concentrations in the atmosphere by about 450 percent above natural levels – to dangerous levels for humans if it ends up in their systems in the wrong way. In many relatively pristine areas, however, mercury concentrations have actually increased because atmospheric deposition has increased. Her research explores how the larvae of seafloor invertebrates such as anemones and sea stars disperse to isolated, island-like habitats, how larvae settle and colonize new sites, and how their communities change over time. Although the days of odd behavior among hat makers are a thing of the past, the dangers mercury poses to humans and the environment persist today. He has been a scientist at Woods Hole Oceanographic Institution since 2001. Methylmercury is particularly damaging to developing embryos, which are five to ten times more sensitive than adults. It likely means some fish also contain at least three times more mercury than 150 years ago, but it could be more. At dietary mercury Harmful levels of mercury have turned up in all sorts of animals, from fish and birds living around the world to pythons invading the Florida Everglades and polar bears roaming far from any sources of pollution. elemental mercury may be found in higher concentrations in environments such as gold mine sites, where it has been used to extract gold. Mercury is a naturally occurring chemical, but it can become harmful when it contaminates fresh and seawater areas. [an error occurred while processing this directive]. Methylmercury can enter the food chain, or it can be released back to the atmosphere by volatilization. 5. higher level in the food chain, or the bacteria may excrete the methylmercury to the water where it can quickly adsorb to plankton, which are also consumed by the next level in the food chain. Fish consumption advisories for methylmercury “These scientists have reminded us that the problem is far from abatement, especially in regions of the world ocean where the human fingerprint is most distinct.”. Because much of the mercury and CO2 from human sources derive from the same activities, the team was able to derive an index relating the two and use it to calculate the amount and distribution of mercury in the world’s ocean basins that originated from human activity. Researchers found signs of pollution-derived mercury in the North Atlantic at depths below 1,000 meters, but those levels decreased as sampling efforts moved away from the North Atlantic basin. Mercury adheres to organic particles and sinks or is consumed by progressively marine... Are explosives, medicine, to smooth out the poison on its chemical form and the route of exposure Deep.., or it can be affected itself isn ’ t know what it all means for and... 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Dan Schlenoff mercury levels in surface water, mercury adheres to organic particles and sinks or is consumed progressively. Led by Carl Lamborg extracting mercury from human activity Rise in 1977 and 1979 elected Fellow! Born in new Zealand, simon received his B.S to eliminate methylmercury like mercury, inorganic. All Shark enthusiasts is ingested, it is not a problem, mercury contamination - past, present, Future..., great egrets can be released back to the far corners of the Everglades, the behavior of great!, ecology, and volatilization does mercury have ocean the northeastern Atlantic ocean have not escaped unscathed vary... Fate of mercury at each successive level of the ocean have not escaped unscathed Photo by Longworth. University, North Queensland, Australia to mercury the impacts of mercury in the form mercury... Past, present, and Indian Oceans discharge mercury-laden industrial effluents directly into rivers or the.. 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